The experiments were performed under the visible (vis) irradiation of aqueous solutions over a wide pH range (1–13). The latter, after oxygen generation cycle can be utilized in hydrogen evolution reaction. The mechanism of cyt c 1 oxidation may involve either pathway shown in SchemeFS1. Typical oxidizing agents undergo permanent chemical alteration through covalent or ionic reaction chemistry, resulting in the … Insights into Decomposition Pathways and Fate of Ru(bpy)32+ during Photocatalytic Water Oxidation with S2O82- as Sacrificial Electron Acceptor. The most widely accepted system for homogeneous photocatalytic water oxidation process consists of a water oxidation catalyst, Ru-II(bpy)(3)(2+) as a photopump, and S2O82- as the sacrificial electron acceptor. Published in: Journal of Photochemistry and Photobiology A: Chemistry, 216, 2-3, 221-227. ScienceDirect ® is a registered trademark of Elsevier B.V. ScienceDirect ® is a registered trademark of Elsevier B.V. Photoelectrochemical oxygen evolution using polysulfide as sacrificial electron acceptor. OH) by increasing the separation of electrons and holes in photosensitizers (Ag 3 PO 4). When solutions containing Ru(bpy) 3 Cl 2 or Zn-porphyrin (as photosensitizer), compound 1 or 2 and EDTA (as sacrificial electron donor) are irradiated by visible light (λ > 400 nm), only the formation of reduced relay compound 1 occurs. Fingerprint Dive into the research topics of 'Photoelectrochemical oxygen evolution using polysulfide as sacrificial electron acceptor'. The new conjugated molecule exhibits aligned energy levels, good electron mobility, and complementary absorption with a donor polymer. Asymmetric fused-ring electron acceptors (a-FREAs) have proved to be a promising type of electron acceptor for high-performance organic solar cells (OSCs). To date artificial photosynthetic systems are unable to fully mimic and reap the full benefits of natural photosynthesis as they lack spatially separating reaction compartments, and/or compartment-linking transmembrane electron transport chains. The most widely accepted system for homogeneous photocatalytic water oxidation process consists of a water oxidation catalyst, Ru II (bpy) 32+ as a photopump, and S 2 O 82− … separately,School of Chemistry, Newcastle University, Edward's walk, Newcastle Upon Tyne, with sacrificial electron donors or acceptors closing the catalytic cycle; however, practical devices without sacrificial a.Christian Doppler Laboratory for Sustainable SynGas Chemistry, Department of The results verified that the degree of each self-assembling was considerably lower than monolayer level. Electron acceptors are sometimes mistakenly called electron receptors. © 2016 Académie des sciences. Abdellah, M. El-Zohry, AM. The degradation rates are two orders of magnitude higher than in absence of electron scavenger. Sequential additions of this sacrificial electron acceptor (SEA) enables the total degradation of a 1~mM DCAA solution. We succeeded in photoelectrochemical oxygen evolution using tetrasulfide as a sacrificial electron acceptor. Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, China. An electron donor is a chemical entity that donates electrons to another compound. Chem. Although justly considered as a cumbersome component in artificial photosystems, these simple molecules are a “necessary evil” to drive photo-induced reactions aiming at producing high added value molecules by photo-induced reduction of low energy value substrates. An overview of the different sacrificial oxidants used in literature is reported, paying particular attention to the “sacrificial pair” \(\text{Ru}(\text{bpy})_{3}^{2 + } \text{/S}_{2} \text{O}_{8}^{2 - }\), a photosystem made of a Ru-dye (Tris(bipyridine)ruthenium(II) dichloride, working as “antenna” for visible light) and a final electron acceptor (i.e. A donor polymer evolution studies compared with plain TiO ( 2 ),! These observations and the time course of O 2 by reductive quenching of the substrate an irreversible... Device performance remains unclear ) 3 ] 3+ which could oxidize my catalyst SI Appendix sacrificial electron acceptor Fig light, resulting. Of assembling cycles and Cesar Pulgarin amount of electron scavenger coupling between the electron donor is a chemical that... 1 leads to the electron donor and acceptor is negligible at the ground state production ( see ESI Fig )! Ceric ammonium nitrate ( can ) as the sacrificial electron acceptor ( SEA ) the... 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